Pressure-induced phase transition of wulfenite

LIU Ying-Xin; QIN Shan; WU Jing; LI Xiao-Dong; LI Yan-Chun; LIU Jing

doi:10.1088/1674-1137/33/11/019

Chinese Physics C> 2009, Vol. 33> Issue(11) : 1023-1027 DOI: 10.1088/1674-1137/33/11/019

Pressure-induced phase transition of wulfenite

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Abstract：
The in-situ high-pressure structures of wulfenite have been investigated by means of angular dispersive X-ray diffraction with diamond anvil cell and synchrotron radiation. In the pressure up to 22.9 GPa, a pressure-induced scheelite-to-fergusonite transition is observed at about 10.6 GPa. The pressure dependence for the lattice parameters of wulfenite is reported, and the axial compression coefficients Ka₀=－1.36×10^－3 GPa^－1 and Kc₀= －2.78×10^－3GPa^－1 are given. The room-temperature isothermal bulk modulus is also obtained by fitting the P-V data using the Murnaghan equation of state.

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LIU Ying-Xin, QIN Shan, WU Jing, LI Xiao-Dong, LI Yan-Chun and LIU Jing. Pressure-induced phase transition of wulfenite[J]. Chinese Physics C, 2009, 33(11): 1023-1027. doi: 10.1088/1674-1137/33/11/019

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Received: 2008-12-18
Revised: 2009-03-30

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Pressure-induced phase transition of wulfenite

Corresponding author: QIN Shan,

Received Date: 2008-12-18

Accepted Date: 2009-03-30

Available Online: 2009-11-05

Abstract:

The in-situ high-pressure structures of wulfenite have been investigated by means of angular dispersive X-ray diffraction with diamond anvil cell and synchrotron radiation. In the pressure up to 22.9 GPa, a pressure-induced scheelite-to-fergusonite transition is observed at about 10.6 GPa. The pressure dependence for the lattice parameters of wulfenite is reported, and the axial compression coefficients Ka₀=－1.36×10^－3 GPa^－1 and Kc₀= －2.78×10^－3GPa^－1 are given. The room-temperature isothermal bulk modulus is also obtained by fitting the P-V data using the Murnaghan equation of state.

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Pressure-induced phase transition of wulfenite

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