Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES

BAO Liang-Man; ZHANG Gui-Lin; ZHANG Yuan-Xun; LI Yan; LIN Jun; LIU Wei; CAO Qing-Chen; ZHAO Yi-Dong; MA Chen-Yan; HAN Yong

doi:10.1088/1674-1137/33/11/016

Chinese Physics C> 2009, Vol. 33> Issue(11) : 1010-1015 DOI: 10.1088/1674-1137/33/11/016

Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES

Abstract
HTML
Reference
Related

PDF

Abstract：
The impact of coal-burning emission on sulfur in camphor leaves was investigated using Proton Induced X-ray Emission (PIXE) and synchrotron radiation technique X-ray Absorption Near-Edge Structure (XANES) spectroscopy. The PIXE results show that the sulfur concentrations in the leaves collected at the polluted site are significantly higher than those in controls. The Sulfur XANES spectra show the presence of organic (disulfides, thiols, thioethers, sulfonates and sulfoxides) and inorganic sulfur (sulfates) in the leaves. The inorganic sulfur in the leaves of camphor tree polluted by coal combustion is 15% more than that of the control site. The results suggest that the long-term coal-burning pollution resulted in an enhanced content of the total sulfur and sulfate in the leaves, and the uptake of sulfur by leaves had exceeded the metabolic requirement of plants and the excess of sulfur was stored as SO₄^2－. It can monitor the sulfur pollution in atmosphere.

References

[1]

. CHAN K C, YAO X. Atmos. Environ., 2008, 42: 1-422. Andreae M O, Crutzen P J. Science, 1997, 276: 1052-10583. Akimoto H. Science, 2003, 302: 1716-17194. Beckett K P, Freer-smith P H, Taylor G. Environ. Pollut.,1998, 99: 347-3605. Alfani A, Baldantoni D, Maisto G et al. Environ. Pollut.,2000, 109: 119-1296. Cicek A, Koparal A S. Chemosphere, 2004, 57: 1031-10367. Agrawal A, Singh J. Environ. Monit. Asses., 1998, 60:261-2828. Jalilehvand F. Soc. Rev.,2006, 35: 1256-12689. Cicek A, Koparal A S. Chemosphere, 2004, 57: 1031-103610. BAO Liang-Man, LIN Jun, LIU Wei et al. Beijing Syn-chrotron Radiation Facility Activity Report, 2007: 84-86(in Chinese)11. Vairavamurthy A. X-ray Spectrom., 1998, 54(12): 2009-201712. XIA K, Weesner F, Bleam W F et al. Soil Sci.Soc. Am. J.,1998, 62(5): 1240-124613. Waldo G S, Robert M K, Carlson M K et al. GeochimCosmochim Acta, 1991, 55: 801-81414. Ravel B, Newville M. J. Synchrotron Radiat., 2005, 12(4):537-54115. Hu man G. P, Huggins F E, Mitra S et al. Energy Fuels,1989, 3(2): 200-20516. Hu man G P, Mitra S, Huggins F E et al. Energy Fuels,1991, 5(4): 574-58117. Hell R. FEBS Letters, 1998, 441: 11-1418. Schmidt S, Jager K. Annu. Rev. Plant Physiol. Plant Mol.Biol., 1992, 43: 325-49

[1]	Hong-Bin Liu , Hu-Cheng Chen , Kai Chen , James Kierstead , Francesco Lanni , Helio Takai , Ge Jin . Development of an ADC radiation tolerance characterization system for the upgrade of the ATLAS LAr calorimeter. Chinese Physics C, 2017, 41(2): 026101. doi: 10.1088/1674-1137/41/2/026101
[2]	WANG Jie , ZHANG Bo , XU Yan-Hui , WEI Wei , FAN Le , PEI Xiang-Tao , HONG Yuan-Zhi , WANG Yong . Deposition and characterization of TiZrV-Pd thin films by dc magnetron sputtering. Chinese Physics C, 2015, 39(12): 127007. doi: 10.1088/1674-1137/39/12/127007
[3]	DU Ying-Shuai , YUE Qian , LIU Yi-Bao , CHEN Qing-Hao , LI Jin , CHENG Jian-Ping , KANG Ke-Jun , LI Yuan-Jing , LI Yu-Lan , MA Hao , XING Hao-Yang , YU Xun-Zhen , ZENG Zhi . Characterization of large area photomultiplier ETL 9357FLB for liquid argon detector. Chinese Physics C, 2014, 38(7): 076003. doi: 10.1088/1674-1137/38/7/076003
[4]	B. Spataro , A. Marcelli , S. Sarti , V. A. Dolgashev , S. Tantawi , A. D. Yeremian , M. G. Grimaldi , L. Romano , F. Ruffino , R. Parodi , G. Cibin , C. Marrelli , M. Migliorati , C. Caliendo0 . Molybdenum sputtering film characterization for high gradient accelerating structures. Chinese Physics C, 2013, 37(9): 097005. doi: 10.1088/1674-1137/37/9/097005
[5]	LIU Li-Juan , LIU Hui-Jun , CUI Ming-Qi , HU Yong-Feng , ZHENG Lei , ZHAO Yi-Dong , MA Chen-Yan , XI Shi-Bo , YANG Dong-Liang , GUO Zhi-Ying , WANG Jie . Determination of the calcium species in coal chars by Ca K-edge XANES analysis. Chinese Physics C, 2013, 37(2): 028003. doi: 10.1088/1674-1137/37/2/028003
[6]	WANG De-Hong , HAO Jun-Jie , XING Xue-Qing , MO Guang , GONG Yu , WU Zhong-Hua , . Characterization of the nanopore structures of PAN-based carbon fiber precursors by small angle X-ray scattering. Chinese Physics C, 2011, 35(9): 870-874. doi: 10.1088/1674-1137/35/9/016
[7]	ZHENG Lei , ZHAO Yi-Dong , TANG Kun , MA Chen-Yan , HAN Yong , CUI Ming-Qi . Total electron yield mode for XANES measurements in the energy region of 2.1--6.0 keV. Chinese Physics C, 2011, 35(2): 199-202. doi: 10.1088/1674-1137/35/2/018
[8]	PENG Yue-Mei , XU Gang . Analytical transfer matrix of a quadrupole fringe. Chinese Physics C, 2011, 35(11): 1047-1052. doi: 10.1088/1674-1137/35/11/013
[9]	HUANG Yu-Fei , LI Guang-Liang . Transfer matrix for the open chain from giant gravitons. Chinese Physics C, 2010, 34(7): 949-952. doi: 10.1088/1674-1137/34/7/004
[10]	DONG Jian-Min , ZHANG Hong-Fei , ZUO Wei , LI Jun-Qing . Unified fission model for proton emission. Chinese Physics C, 2010, 34(2): 182-185. doi: 10.1088/1674-1137/34/2/005
[11]	WANG Xiao-Xiong , LI Hong-Nian , WANG Peng , NI Jing-Fu , WANG Jia-Ou , QIAN Hai-Jie , KURASH Ibrahim , . Charge transfer of 1 ML C₆₀/Ag(100). Chinese Physics C, 2009, 33(11): 996-1000. doi: 10.1088/1674-1137/33/11/013
[12]	ZHAO Ting , GAO Bin , LIU Lei , YE Qing , CHU Wang-Sheng , WU Zi-Yu . Theoretical XANES spectra for C₇₆ isomers. Chinese Physics C, 2009, 33(11): 954-959. doi: 10.1088/1674-1137/33/11/005
[13]	LIN Jun , BAO Liang-Man , LIU Wei , LI Yan , LI Yu-Lan , MA Chen-Yan , ZHAO Yi-Dong . Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES. Chinese Physics C, 2009, 33(11): 965-968. doi: 10.1088/1674-1137/33/11/007
[14]	BAO Liang-Man , LIN Jun , LIU Wei , LU Wen-Zhong , ZHANG Gui-Lin , LI Yan , MA Chen-Yan , ZHAO Yi-Dong , HE Wei , HU Tian-Dou . Investigation of sulfur speciation in particles from small coal-burning boiler by XANES spectroscopy. Chinese Physics C, 2009, 33(11): 1001-1005. doi: 10.1088/1674-1137/33/11/014
[15]	ZHU Jian-Yu , XU Fu-Rong . Spin-orbit potential in sulfur isotopes. Chinese Physics C, 2008, 32(S2): 155-157.
[16]	GUO Xiao-Yun , CHU Wang-Sheng , GONG Wei-Min , DONG Yu-Hui , XIE Ya-Ning , YANG Fei-Fei , Maurizio Benfatto , WU Zi-Yu . MXAN Analysis of the XANES Energy Region of LiPDF. Chinese Physics C, 2007, 31(2): 199-203.
[17]	HU Rong , WU Zi-Yu , LIU Jing , XIE Ya-Ning , HU Tian-Dou , ZHANG Jing , FENG Wei-Yue , CHAI Zhi-Fang . XANES Investigation of Chromium Valence State in Yeast Biomass. Chinese Physics C, 2004, 28(1): 100-103.
[18]	JI Yun-Liang , HU Rong , WU Zi-Yu , GUO Lin , XU Hui-Bin , ZHANG Jing , XIE Ya-Ning , HU Tian-Dou . XANES Investigation of Synthesized Nano-ZnO Capped by DDAB. Chinese Physics C, 2003, 27(4): 367-370.
[19]	Fan Qinmin , Zhong Ming . The Use of Numerical Calculation in the Analysis of Standardless Thick Target PIXE. Chinese Physics C, 1988, 12(S2): 109-116.
[20]	FAN Qin-Min , Zhong Ming . THE NUMERICAL CALCULATION USED IN THICK TARGET PIXE ANALYSES. Chinese Physics C, 1988, 12(1): 6-11.

Access

Get Citation

BAO Liang-Man, ZHANG Gui-Lin, ZHANG Yuan-Xun, LI Yan, LIN Jun, LIU Wei, CAO Qing-Chen, ZHAO Yi-Dong, MA Chen-Yan and HAN Yong. Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES[J]. Chinese Physics C, 2009, 33(11): 1010-1015. doi: 10.1088/1674-1137/33/11/016

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2008-12-18
Revised: 2009-03-30

Article Metric

Article Views(2586)
PDF Downloads(604)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES

Corresponding author: BAO Liang-Man,

Received Date: 2008-12-18

Accepted Date: 2009-03-30

Available Online: 2009-11-05

Abstract:

The impact of coal-burning emission on sulfur in camphor leaves was investigated using Proton Induced X-ray Emission (PIXE) and synchrotron radiation technique X-ray Absorption Near-Edge Structure (XANES) spectroscopy. The PIXE results show that the sulfur concentrations in the leaves collected at the polluted site are significantly higher than those in controls. The Sulfur XANES spectra show the presence of organic (disulfides, thiols, thioethers, sulfonates and sulfoxides) and inorganic sulfur (sulfates) in the leaves. The inorganic sulfur in the leaves of camphor tree polluted by coal combustion is 15% more than that of the control site. The results suggest that the long-term coal-burning pollution resulted in an enhanced content of the total sulfur and sulfate in the leaves, and the uptake of sulfur by leaves had exceeded the metabolic requirement of plants and the excess of sulfur was stored as SO₄^2－. It can monitor the sulfur pollution in atmosphere.

HTML

Reference (1)

Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article